LrgpV1, Main, Exploration, bibRecord, 001188

Recent approaches towards the asymmetric synthesis of α,α-disubstituted α-amino acids

Identifieur interne : 001188 ( Main/Exploration ); précédent : 001187; suivant : 001189

Recent approaches towards the asymmetric synthesis of α,α-disubstituted α-amino acids

Auteurs : Henning Vogt [Danemark] ; Stefan Br Se [Allemagne]

Source :

Organic & Biomolecular Chemistry [ 1477-0520 ] ; 2007.

RBID : ISTEX:8198A3749AE56B0CBFBDF7DDFF14781DD4162ACA

Descripteurs français

Wicri :
- topic : Acide.

English descriptors

Abstract

The class of α,α-disubstituted α-amino acids has gained considerable attention in the past decades and continues doing so. The ongoing interest in biological and chemical properties of the substance class has inspired the development of many new methodologies for their asymmetric construction, which have not found their way into the general focus of organic chemistry yet. The aim of this review is to provide an overview of the developments in the field since 1998.

Url:

https://api.istex.fr/document/8198A3749AE56B0CBFBDF7DDFF14781DD4162ACA/fulltext/pdf

DOI: 10.1039/b611091f

Affiliations:

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Le document en format XML

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<term>Alkylation</term>
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<term>Allylic alkylation</term>
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<term>Amino acid</term>
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<term>Asymmetric strecker approach</term>
<term>Asymmetric strecker reaction</term>
<term>Asymmetric synthesis</term>
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<term>Azide</term>
<term>Azlactones</term>
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<term>Carbonyl compounds</term>
<term>Carboxylic group</term>
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<term>Cativiela</term>
<term>Chem</term>
<term>Chiral</term>
<term>Chiral epoxides</term>
<term>Citric acid</term>
<term>Considerable attention</term>
<term>Corresponding acid</term>
<term>Curtius rearrangement</term>
<term>Cyclic</term>
<term>Cyclisation</term>
<term>Deprotonation</term>
<term>Diastereomeric</term>
<term>Diastereomeric ratios</term>
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<term>Etoh</term>
<term>Excellent yields</term>
<term>Glutamate</term>
<term>High enantiomeric</term>
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<term>Hydrocyanic acid</term>
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<term>Organocatalysed</term>
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<term>Oxazinones</term>
<term>Reaction conditions</term>
<term>Reaction rate</term>
<term>Reagent</term>
<term>Rearrangement</term>
<term>Rearrangement reaction</term>
<term>Receptor</term>
<term>Room temperature</term>
<term>Royal society</term>
<term>Schiff</term>
<term>Schiff bases</term>
<term>Schmidt rearrangement</term>
<term>Sharpless</term>
<term>Shibasaki</term>
<term>Shinada</term>
<term>Sodium azide</term>
<term>Spontaneous cyclisation</term>
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<term>Strecker products</term>
<term>Strecker reaction</term>
<term>Subsequent hydrogenation</term>
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<term>Substituents</term>
<term>Sulfonyl azides</term>
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<term>Tetrahedron lett</term>
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<term>Total synthesis</term>
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<term>Acid residues</term>
<term>Acid synthesis</term>
<term>Additional steps</term>
<term>Aldehyde</term>
<term>Alkylation</term>
<term>Allylic</term>
<term>Allylic alkylation</term>
<term>Amination</term>
<term>Amino</term>
<term>Amino acid</term>
<term>Amino acid synthesis</term>
<term>Amino acids</term>
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<term>Asymmetric construction</term>
<term>Asymmetric strecker approach</term>
<term>Asymmetric strecker reaction</term>
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<term>Azlactones</term>
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<term>Carbonyl compounds</term>
<term>Carboxylic group</term>
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<term>Catalyst</term>
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<term>Chem</term>
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<term>Chiral epoxides</term>
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<term>Corresponding acid</term>
<term>Curtius rearrangement</term>
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<term>Cyclisation</term>
<term>Deprotonation</term>
<term>Diastereomeric</term>
<term>Diastereomeric ratios</term>
<term>Diastereomers</term>
<term>Diastereoselective alkylation</term>
<term>Diastereoselectivity</term>
<term>Electrophiles</term>
<term>Enantiomeric</term>
<term>Enantioselectivity</term>
<term>Epoxides</term>
<term>Ester</term>
<term>Etoh</term>
<term>Excellent yields</term>
<term>Glutamate</term>
<term>High enantiomeric</term>
<term>Hydrochloric acid</term>
<term>Hydrocyanic acid</term>
<term>Hydrogenation</term>
<term>Ichikawa</term>
<term>Imine</term>
<term>Kanai</term>
<term>Lett</term>
<term>Ligand</term>
<term>Main product</term>
<term>Maruoka</term>
<term>Meoh</term>
<term>Metabotropic</term>
<term>Metabotropic glutamate receptor antagonists</term>
<term>Naclo2 nah2</term>
<term>Naio4</term>
<term>Nan3</term>
<term>Nucleophilic</term>
<term>Nucleophilic addition</term>
<term>Nucleophilic alkylation</term>
<term>Ohfune</term>
<term>Open access</term>
<term>Organocatalysed</term>
<term>Oxazinone</term>
<term>Oxazinones</term>
<term>Reaction conditions</term>
<term>Reaction rate</term>
<term>Reagent</term>
<term>Rearrangement</term>
<term>Rearrangement reaction</term>
<term>Receptor</term>
<term>Room temperature</term>
<term>Royal society</term>
<term>Schiff</term>
<term>Schiff bases</term>
<term>Schmidt rearrangement</term>
<term>Sharpless</term>
<term>Shibasaki</term>
<term>Shinada</term>
<term>Sodium azide</term>
<term>Spontaneous cyclisation</term>
<term>Stereoselectivity</term>
<term>Strecker</term>
<term>Strecker products</term>
<term>Strecker reaction</term>
<term>Subsequent hydrogenation</term>
<term>Substance class</term>
<term>Substituents</term>
<term>Sulfonyl azides</term>
<term>Synlett</term>
<term>Tetrahedron</term>
<term>Tetrahedron lett</term>
<term>Toluene</term>
<term>Total synthesis</term>
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<front><div type="abstract">The class of α,α-disubstituted α-amino acids has gained considerable attention in the past decades and continues doing so. The ongoing interest in biological and chemical properties of the substance class has inspired the development of many new methodologies for their asymmetric construction, which have not found their way into the general focus of organic chemistry yet. The aim of this review is to provide an overview of the developments in the field since 1998.</div>
</front>
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Recent approaches towards the asymmetric synthesis of α,α-disubstituted α-amino acids

Recent approaches towards the asymmetric synthesis of α,α-disubstituted α-amino acids

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri